Reversible Reactions
نویسندگان
چکیده
منابع مشابه
Equilibration in Reversible Bimolecular Reactions
Fast reversible pseudo-unimolecular reactions do not approach equilibrium in the simple exponential fashion predicted by chemical rate equations. Many-body effects in bimolecular reactions have been revealed in an extensive series of Brownian simulations, showing up to three distinct phases in the approach to equilibrium. Recent theoretical developments are compared with the simulation as well ...
متن کاملUnified theory of reversible target reactions
We discuss two fundamental reversible diffusion influenced reactions: ~i! A1B C and ~ii! A 1B C1D. In the pseudo-unimolecular case, we prove that reaction ~i! is a special case of ~ii!, which thus constitutes a unified reversible problem of multiparticle kinetics. For static A and C ~the ‘‘target’’ limit!, we suggest to treat this problem as follows. First we generalize the Smoluchowski theory ...
متن کاملDynamics of reversible electron transfer reactions
The dynamics of reversible electron transfer reactions in Debye solvents are studied by employing two coupled diffusion-reaction equations with the rate constants depending on the reaction coordinate. The equations are solved analytically in four limiting cases: fast and slow reactions as well as wide and narrow reaction windows. A general solution for the survival probabilities is obtained by ...
متن کاملReversible, cooperative reactions of yeast vacuole docking.
Homotypic yeast vacuole fusion occurs in three stages: (i) priming reactions, which are independent of vacuole clustering, (ii) docking, in which vacuoles cluster and accumulate fusion proteins and fusion regulatory lipids at a ring-shaped microdomain surrounding the apposed membranes of each docked vacuole, where fusion will occur, and (iii) bilayer fusion/compartment mixing. These stages requ...
متن کاملInterplay of reversible chain transfer and comonomer incorporation reactions in coordination copolymerization of ethylene/1–hexene
Coordinative chain transfer polymerization (CCTP) has opened a new path for the development of novel products like olefin block copolymers and chain-end functional polyolefins. However, conflicting results are frequently reported on the catalyst performance including activity and comonomer selectivity under CCTP conditions. Here we have selected two catalysts including rac-ethylenebis(1-η5-inde...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Physical Chemistry
سال: 1899
ISSN: 0092-7325,1541-5740
DOI: 10.1021/j150010a004